Volume 2 Issue 1
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Chunxi Tian, Kun Qin, Liumin Suo. Concentrated electrolytes for rechargeable lithium metal batteries[J]. Materials Futures, 2023, 2(1): 012101. doi: 10.1088/2752-5724/acac68
Citation: Chunxi Tian, Kun Qin, Liumin Suo. Concentrated electrolytes for rechargeable lithium metal batteries[J]. Materials Futures, 2023, 2(1): 012101. doi: 10.1088/2752-5724/acac68
shu
Topical Review •
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Concentrated electrolytes for rechargeable lithium metal batteries

© 2023 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 2, Number 1
  • Received Date: 2022-10-24
  • Accepted Date: 2022-12-17
  • Rev Recd Date: 2022-11-30
  • Publish Date: 2023-01-24
doi: 10.1088/2752-5724/acac68
  • 1.

    Institute of Physics, Chinese Academy of Sciences, Beijing National Laboratory for Condensed Matter Physics, Beijing 100190, People’s Republic of China

  • 2.

    Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, People’s Republic of China

  • Author to whom any correspondence should be addressed.

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    Abstract
  • Traditional lithium-ion batteries with graphite anodes have gradually been limited by the glass ceiling of energy density. As a result, lithium metal batteries (LMBs), regarded as the ideal alternative, have attracted considerable attention. However, lithium is highly reactive and susceptible to most electrolytes, resulting in poor cycle performance. In addition, lithium grows Li dendrites during charging, adversely affecting the safety of LMBs. Therefore, LMBs are more sensitive to the chemical composition of electrolytes and their relative ratios (concentrations). Recently, concentrated electrolytes have been widely demonstrated to be friendly to lithium metal anodes (LMAs). This review focuses on the progress of concentrated electrolytes in LMBs, including the solvation structure varying with concentration, unique functions in stabilizing the LMA, and their interfacial chemistry with LMA.
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