Enhancing performance and longevity of solid-state zinc-iodine batteries with fluorine-rich solid electrolyte interphase

Yongxin Huang; Yiqing Wang; Xiyue Peng; Tongen Lin; Xia Huang; Norah S Alghamdi; Masud Rana; Peng Chen; Cheng Zhang; Andrew K Whittaker; Lianzhou Wang; Bin Luo

doi:10.1088/2752-5724/ad50f1

Volume 3 Issue 3

September 2024

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Article Contents

Yongxin Huang, Yiqing Wang, Xiyue Peng, Tongen Lin, Xia Huang, Norah S Alghamdi, Masud Rana, Peng Chen, Cheng Zhang, Andrew K Whittaker, Lianzhou Wang, Bin Luo. Enhancing performance and longevity of solid-state zinc-iodine batteries with fluorine-rich solid electrolyte interphase[J]. Materials Futures, 2024, 3(3): 035102. doi: 10.1088/2752-5724/ad50f1

Citation:

Yongxin Huang, Yiqing Wang, Xiyue Peng, Tongen Lin, Xia Huang, Norah S Alghamdi, Masud Rana, Peng Chen, Cheng Zhang, Andrew K Whittaker, Lianzhou Wang, Bin Luo. Enhancing performance and longevity of solid-state zinc-iodine batteries with fluorine-rich solid electrolyte interphase[J]. Materials Futures, 2024, 3(3): 035102. doi: 10.1088/2752-5724/ad50f1

Citation:

Yongxin Huang, Yiqing Wang, Xiyue Peng, Tongen Lin, Xia Huang, Norah S Alghamdi, Masud Rana, Peng Chen, Cheng Zhang, Andrew K Whittaker, Lianzhou Wang, Bin Luo. Enhancing performance and longevity of solid-state zinc-iodine batteries with fluorine-rich solid electrolyte interphase[J]. Materials Futures, 2024, 3(3): 035102. doi: 10.1088/2752-5724/ad50f1

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Enhancing performance and longevity of solid-state zinc-iodine batteries with fluorine-rich solid electrolyte interphase

Materials Futures, Volume 3, Number 3

Received Date: 2024-04-09
Accepted Date: 2024-05-26
Revised Date: 2024-05-19
Publish Date: 2024-06-17

Article information

doi: 10.1088/2752-5724/ad50f1

1.
Australian Institute for Bioengineering and Nanotechnology (AIBN), The University of Queensland, Brisbane, QLD, 4072, Australia
2.
School of Chemical Engineering, The University of Queensland, Brisbane, QLD, 4072, Australia
3.
School of Chemistry and Molecular Biosciences, Faculty of Science, The University of Queensland, Brisbane, QLD, 4072, Australia
4.
Department of Chemistry, Faculty of Science, Imam Mohammad Ibn Saud Islamic University (IMSIU), Riyadh 11564, Saudi Arabia
Authors to whom any correspondence should be addressed.

More Information

Corresponding author: E-mail: c.zhang3@uq.edu.au; E-mail: b.luo1@uq.edu.au

Abstract

Abstract

AbstractRechargeable zinc-iodine (ZnI₂) batteries have gained popularity within the realm of aqueous batteries due to their inherent advantages, including natural abundance, intrinsic safety, and high theoretical capacity. However, challenges persist in their practical applications, notably battery swelling and vulnerability in aqueous electrolytes, primarily linked to the hydrogen evolution reaction and zinc dendrite growth. To address these challenges, this study presents an innovative approach by designing a solid-state ZnI₂ battery featuring a solid perfluoropolyether based polymer electrolyte. The results demonstrate the formation of a solid electrolyte interphase layer on zinc, promoting horizontal zinc growth, mitigating dendrite penetration, and enhancing battery cycle life. Moreover, the solid electrolyte hinders the iodine ion shuttle effect, reducing zinc foil corrosion. Symmetric batteries employing this electrolyte demonstrate excellent cycle performance, maintaining stability for approximately 5000 h at room temperature, while solid-state ZnI₂ batteries exhibit over 7000 cycles with a capacity retention exceeding 72.2%. This work offers a promising pathway to achieving reliable energy storage in solid-state ZnI₂ batteries and introduces innovative concepts for flexible and wearable zinc batteries.
- zinc-iodine battery,
- solid electrolyte,
- zinc metal anode,
- electrolyte interphase,
- shuttle effect

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Conflict of interest

The authors declare no conflict of interest.

Author contributions

Y Huang and Y Wang contributed equally to this work. Y Huang conceived this work and conducted device fabrication and electrochemical measurements. Y, Wang carried out the material synthesis and characterisations. B Luo and C Zhang obtained funding and supervised the project. T Lin, X Huang, N, Alghamdi, M Rana, P Chen, supported the experiments and discussed the results. Y Huang and Y Wang wrote the manuscript with further revision from C Zhang, A Whittaker, L Wang, and B Luo. All authors have commented on the work.

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