Volume 3 Issue 3
September  2024
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Yanshen Gao, Jiaxin Li, Yumeng Hua, Qingshan Yang, Rudof Holze, Ewa Mijowska, Paul K Chu, Xuecheng Chen. Recent advances of metal fluoride compounds cathode materials for lithium ion batteries: a review[J]. Materials Futures, 2024, 3(3): 032101. doi: 10.1088/2752-5724/ad4572
Citation: Yanshen Gao, Jiaxin Li, Yumeng Hua, Qingshan Yang, Rudof Holze, Ewa Mijowska, Paul K Chu, Xuecheng Chen. Recent advances of metal fluoride compounds cathode materials for lithium ion batteries: a review[J]. Materials Futures, 2024, 3(3): 032101. doi: 10.1088/2752-5724/ad4572
shu
Topical Review •
OPEN ACCESS

Recent advances of metal fluoride compounds cathode materials for lithium ion batteries: a review

© 2024 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 3, Number 3
  • Received Date: 2024-01-30
  • Accepted Date: 2024-04-29
  • Revised Date: 2024-04-18
  • Publish Date: 2024-06-25
doi: 10.1088/2752-5724/ad4572
  • 1.

    Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, Szczecin, Piastów Ave. 42, Szczecin 71-065, Poland

  • 2.

    Department of Physics, Department of Materials Science and Engineering, and Department of Biomedical Engineering, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong Special Administrative Region of China, People’s Republic of China

  • 3.

    Chemnitz University of Technology, Institut für Chemie, AG Elektrochemie, 09107 Chemnitz, Germany

  • Authors to whom any correspondence should be addressed.

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    Abstract
  • AbstractAs the most successful new energy storage device developed in recent decades, lithium-ion batteries (LIBs) are ubiquitous in the modern society. However, current commercial LIBs comprising mainly intercalated cathode materials are limited by the theoretical energy density which cannot meet the high storing energy demanded by renewable applications. Compared to intercalation-type cathode materials, low-cost conversion-type cathode materials with a high theoretical specific capacity are expected to boost the overall energy of LIBs. Among the different conversion cathode materials, metal fluorides have become a popular research subject for their environmental friendliness, low toxicity, wide voltage range, and high theoretical specific capacity. In this review, we compare the energy storage performance of intercalation and conversion cathode materials based on thermodynamic calculation and summarize the main challenges. The common conversion-type cathode materials are described and their respective reaction mechanisms are discussed. In particular, the structural flaws and corresponding solutions and strategies are described. Finally, we discussed the prospective of metal fluorides and other conversion cathode materials to guide further research in this important field.
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