Volume 2 Issue 3
August  2023
Turn off MathJax
Article Contents
Jiahao Zhang, Chao Ye, Yao Liao, Caihong Sun, Youlian Zeng, Jing Xiao, Zhi Chen, Wei Liu, Xiukang Yang, Ping Gao. Thiophene-functionalized porphyrin complexes as high performance electrodes for sodium ion batteries[J]. Materials Futures, 2023, 2(3): 035101. doi: 10.1088/2752-5724/acdd86
Citation: Jiahao Zhang, Chao Ye, Yao Liao, Caihong Sun, Youlian Zeng, Jing Xiao, Zhi Chen, Wei Liu, Xiukang Yang, Ping Gao. Thiophene-functionalized porphyrin complexes as high performance electrodes for sodium ion batteries[J]. Materials Futures, 2023, 2(3): 035101. doi: 10.1088/2752-5724/acdd86
shu
Paper •
OPEN ACCESS

Thiophene-functionalized porphyrin complexes as high performance electrodes for sodium ion batteries

© 2023 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 2, Number 3
  • Received Date: 2023-03-26
  • Accepted Date: 2023-06-04
  • Rev Recd Date: 2023-05-18
  • Publish Date: 2023-07-13
doi: 10.1088/2752-5724/acdd86
  • 1.

    Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China

  • 2.

    College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518071, People’s Republic of China

  • 3.

    Yiyang Hongyuan Rare Earth Co., Ltd, Yiyang 413001, People’s Republic of China

  • Authors to whom any correspondence should be addressed.

More Information
    Abstract
  • Organic sodium-ion batteries (OSIBs) using eco-friendly organic materials as electrodes have recently received much attention. However, the practical applications of OSIBs are generally limited by the inherent disadvantages of organic electrodes, such as their low conductivity, poor stability, and high solubility in electrolytes. Herein, we presented [5, 10, 15, 20-tetrathienylporphinato] M (II) (MTTP, M=2H, Ni) as new electrode materials in sodium-organic batteries. The incorporation of thiophene functionalized groups and nickel (Ⅱ) ion in the molecular design of porphyrins enabled stable and excellent electrochemical performance in sodium storage systems. Benefiting from multiple charge storage sites and bipolar characteristics, the NiTTP anode has a reversible capacity of 434 mAh g-1 at a current density of 25 mA g-1. An excellent long-term cycling stability and high average voltage were obtained when NiTTP was used as a cathode. In a symmetrical battery, where NiTTP was used as both cathode and anode materials, a high average voltage of 2.3 V and a practical energy density of 93 Wh kg-1 was achieved. These results suggest that the thiophene-based porphyrin derivatives would be promising electrode materials for long-term organic sodium ion batteries for green and stable energy storage.
    • FullText(HTML)
  • loading

    • Conflict of interest

    There are no conflicts to declare.

    References(47)
  • [1]
    Neumann J, Petranikova M, Meeus M, Gamarra J D, Younesi R, Winter M, Nowak S 2022 Recycling of lithium-ion batteriescurrent state of the art, circular economy, and next generation recycling Adv. Energy Mater. 12 2102917 doi: 10.1002/aenm.202102917
    [2]
    Lai X, Chen Q, Tang X, Zhou Y, Gao F, Guo Y, Bhagat R, Zheng Y 2022 Critical review of life cycle assessment of lithium-ion batteries for electric vehicles: a lifespan perspective eTransportation 12 100169 doi: 10.1016/j.etran.2022.100169
    [3]
    Schomberg A C, Bringezu S, Flrke M 2021 Extended life cycle assessment reveals the spatially-explicit water scarcity footprint of a lithium-ion battery storage Commun. Earth Environ. 2 11 doi: 10.1038/s43247-020-00080-9
    [4]
    Muralidharan N, Self E C, Dixit M, Du Z, Essehli R, Amin R, Nanda J, Belharouak I 2022 Next-generation cobalt-free cathodesa prospective solution to the battery industry’s cobalt problem Adv. Energy Mater. 12 2103050 doi: 10.1002/aenm.202103050
    [5]
    Zhang J, Jia K, Li X, Liu X, Zhu L, Wu F 2022 A furan-based organic cathode material for high-performance sodium ion batteries J. Mater. Chem. A 10 10062-8 doi: 10.1039/D2TA01497A
    [6]
    Holguin K, Mohammadiroudbari M, Qin K, Luo C 2021 Organic electrode materials for non-aqueous, aqueous, and all-solid-state Na-ion batteries J. Mater. Chem. A 9 19083-115 doi: 10.1039/D1TA00528F
    [7]
    Wu L, Hu X, Qian J, Pei F, Wu F, Mao R, Ai X, Yang H, Cao Y 2014 Sb-C nanofibers with long cycle life as an anode material for high-performance sodium-ion batteries Energy Environ. Sci. 7 323-8 doi: 10.1039/C3EE42944J
    [8]
    Balogun M-S, Luo Y, Qiu W, Liu P, Tong Y 2016 A review of carbon materials and their composites with alloy metals for sodium ion battery anodes Carbon 98 162-78 doi: 10.1016/j.carbon.2015.09.091
    [9]
    Wang S, Xia L, Yu L, Zhang L, Wang H, Lou X W 2016 Free-standing nitrogen-doped carbon nanofiber films: integrated electrodes for sodium-ion batteries with ultralong cycle life and superior rate capability Adv. Energy Mater. 6 1502217 doi: 10.1002/aenm.201502217
    [10]
    Jiang Y, Hu M, Zhang D, Yuan T, Sun W, Xu B, Yan M 2014 Transition metal oxides for high performance sodium ion battery anodes Nano Energy 5 60-66 doi: 10.1016/j.nanoen.2014.02.002
    [11]
    Zhao C, et al 2017 Ultrafine MoO2-carbon microstructures enable ultralong-life power-type sodium ion storage by enhanced pseudocapacitance Adv. Energy Mater. 7 1602880 doi: 10.1002/aenm.201602880
    [12]
    Zhou M, Xu Y, Wang C, Li Q, Xiang J, Liang L, Wu M, Zhao H, Lei Y 2017 Amorphous TiO2 inverse opal anode for high-rate sodium ion batteries Nano Energy 31 514-24 doi: 10.1016/j.nanoen.2016.12.005
    [13]
    Wang J, et al 2022 P2-type layered high-entropy oxides as sodium-ion cathode materials Mater. Futures 1 035104 doi: 10.1088/2752-5724/ac8ab9
    [14]
    Li W, Hu S, Luo X, Li Z, Sun X, Li M, Liu F, Yu Y 2017 Confined amorphous red phosphorus in MOF-derived N-doped microporous carbon as a superior anode for sodium-ion battery Adv. Mater. 29 1605820 doi: 10.1002/adma.201605820
    [15]
    Wang C, Wang L, Li F, Cheng F, Chen J 2017 Bulk bismuth as a high-capacity and ultralong cycle-life anode for sodium-ion batteries by coupling with glyme-based electrolytes Adv. Mater. 29 1702212 doi: 10.1002/adma.201702212
    [16]
    Lao M, Zhang Y, Luo W, Yan Q, Sun W, Dou S X 2017 Alloy-based anode materials toward advanced sodium-ion batteries Adv. Mater. 29 1700622 doi: 10.1002/adma.201700622
    [17]
    Liu T, Yang Y, Cao S, Xiang R, Zhang L, Yu J 2023 Pore perforation of graphene coupled with in situ growth of Co3 Se4 for high-performance Na-ion battery Adv. Mater. 35 2207752 doi: 10.1002/adma.202207752
    [18]
    Bai P, He Y, Zou X, Zhao X, Xiong P, Xu Y 2018 Elucidation of the sodium-storage mechanism in hard carbons Adv. Energy Mater. 8 1703217 doi: 10.1002/aenm.201703217
    [19]
    Yin X, Sarkar S, Shi S, Huang Q-A, Zhao H, Yan L, Zhao Y, Zhang J 2020 Recent progress in advanced organic electrode materials for sodium-ion batteries: synthesis, mechanisms, challenges and perspectives Adv. Funct. Mater. 30 1908445 doi: 10.1002/adfm.201908445
    [20]
    Lu Y, Chen J 2020 Prospects of organic electrode materials for practical lithium batteries Nat. Rev. Chem. 4 127-42 doi: 10.1038/s41570-020-0160-9
    [21]
    Chen X, Feng X, Ren B, Jiang L, Shu H, Yang X, Chen Z, Sun X, Liu E, Gao P 2021 High rate and long lifespan sodium-organic batteries using pseudocapacitive porphyrin complexes-based cathode Nano-Micro Lett. 13 71 doi: 10.1007/s40820-021-00593-8
    [22]
    Wang L Y, Ma C, Wei X, Chang B B, Wang K X, Chen J S 2020 Sodium phthalate as an anode material for sodium ion batteries: effect of the bridging carbonyl group J. Mater. Chem. A 8 8469-75 doi: 10.1039/D0TA01281E
    [23]
    Hupler B, Wild A, Schubert U S 2015 Carbonyls: powerful organic materials for secondary batteries Adv. Energy Mater. 5 1402034 doi: 10.1002/aenm.201402034
    [24]
    Li K, Xu S, Han D, Si Z, Wang H G 2021 Carbonyl-rich poly(pyrene-4,5,9,10-tetraone sulfide) as anode materials for high-performance Li and Na-ion batteries Chem. Asian J. 16 1973-8 doi: 10.1002/asia.202100455
    [25]
    Wang L, Ni Y, Hou X, Chen L, Li F, Chen J 2020 A two-dimensional metal-organic polymer enabled by robust nickel-nitrogen and hydrogen bonds for exceptional sodium-ion storage Angew. Chem., Int. Ed. Engl. 59 22126-31 doi: 10.1002/anie.202008726
    [26]
    Deng W, Shen Y, Qian J, Cao Y, Yang H 2015 A perylene diimide crystal with high capacity and stable cyclability for Na-ion batteries ACS Appl. Mater. Interfaces 7 21095-9 doi: 10.1021/acsami.5b04325
    [27]
    Huang T, Lu D, Ma L, Xi X, Liu R, Wu D 2018 A hit-and-run strategy towards perylene diimide/reduced graphene oxide as high performance sodium ion battery cathode Chem. Eng. J. 349 66-71 doi: 10.1016/j.cej.2018.05.078
    [28]
    Luo C, et al 2018 Reversible redox chemistry of Azo compounds for sodium-ion batteries Angew. Chem., Int. Ed. Engl. 57 2879-83 doi: 10.1002/anie.201713417
    [29]
    Shimizu T, Mameuda T, Toshima H, Akiyoshi R, Kamakura Y, Wakamatsu K, Tanaka D, Yoshikawa H 2022 Application of porous coordination polymer containing aromatic Azo linkers as cathode-active materials in sodium-Ion batteries ACS Appl. Energy Mater. 5 5191-8 doi: 10.1021/acsaem.2c00537
    [30]
    Weeraratne K S, Alzharani A A, El-Kaderi H M 2019 Redox-active porous organic polymers as novel electrode materials for green rechargeable sodium-ion batteries ACS Appl. Mater. Interfaces 11 23520-6 doi: 10.1021/acsami.9b05956
    [31]
    Zhang H, et al 2022 Organic cathode materials for sodium-ion batteries: from fundamental research to potential commercial application Adv. Funct. Mater. 32 2107718 doi: 10.1002/adfm.202107718
    [32]
    Shi R, Liu L, Lu Y, Wang C, Li Y, Li L, Yan Z, Chen J 2020 Nitrogen-rich covalent organic frameworks with multiple carbonyls for high-performance sodium batteries Nat. Commun. 11 178 doi: 10.1038/s41467-019-13739-5
    [33]
    Zhao J, Zhou M, Chen J, Tao L, Zhang Q, Li Z, Zhong S, Fu H, Wang H, Wu L 2021 Phthalocyanine-based covalent organic frameworks as novel anode materials for high-performance lithium-ion/sodium-ion batteries Chem. Eng. J. 425 131630 doi: 10.1016/j.cej.2021.131630
    [34]
    Wu Z, Xie J, Xu Z J, Zhang S, Zhang Q 2019 Recent progress in metal-organic polymers as promising electrodes for lithium/sodium rechargeable batteries J. Mater. Chem. A 7 4259-90
    [35]
    Qin J-H, Xu P, Huang Y-D, Xiao L-Y, Lu W, Yang X-G, Ma L-F, Zang S-Q 2021 High loading of Mn(ii)-metalated porphyrin in a MOF for photocatalytic CO2 reduction in gas-solid conditions Chem. Commun. 57 8468-71 doi: 10.1039/D1CC02847B
    [36]
    Han D, et al 2020 Enhanced photocatalytic activity and photothermal effects of cu-doped metal-organic frameworks for rapid treatment of bacteria-infected wounds Appl. Catal. B 261 118248 doi: 10.1016/j.apcatb.2019.118248
    [37]
    Chiang Y-J, Hsiao Y-H, Chen Y-H, Hung C-M, Chen H-C, Yeh C-Y 2020 All-porphyrin photovoltaics with power conversion efficiency of 7.2% ACS Energy Lett. 5 2641-50 doi: 10.1021/acsenergylett.0c01128
    [38]
    Wu L N, Li M Y, Sui M Y, Huang J C, Sun G Y, Cheng L 2021 Achieve panchromatic absorption for all-small-molecule organic solar cells based on mono-porphyrin molecules by -bridge modification Mater. Today Energy 20 100658 doi: 10.1016/j.mtener.2021.100658
    [39]
    Lv S, et al 2020 Copper porphyrin as a stable cathode for high-performance rechargeable potassium organic batteries ChemSusChem 13 2286-94 doi: 10.1002/cssc.202000425
    [40]
    Gao P, et al 2017 A porphyrin complex as a self-conditioned electrode material for high-performance energy storage Angew. Chem., Int. Ed. 56 10341-6 doi: 10.1002/anie.201702805
    [41]
    Wu X, et al 2022 Thiophene functionalized porphyrin complexes as novel bipolar organic cathodes with high energy density and long cycle life Energy Storage Mater. 46 252-8 doi: 10.1016/j.ensm.2022.01.020
    [42]
    Jeong K, Kim J-M, Kim S H, Jung G Y, Yoo J, Kim S-H, Kwak S K, Lee S-Y 2019 Carbon-nanotube-cored cobalt porphyrin as a 1D nanohybrid strategy for high-performance lithium-ion battery anodes Adv. Funct. Mater. 29 1806937 doi: 10.1002/adfm.201806937
    [43]
    Yang H, et al 2016 High conductive two-dimensional covalent organic framework for lithium storage with large capacity ACS Appl. Mater. Interfaces 8 5366-75 doi: 10.1021/acsami.5b12370
    [44]
    Kumar N A, Gaddam R R, Suresh M, Varanasi S R, Yang D, Bhatia S K, Zhao X S 2017 Porphyrin-graphene oxide frameworks for long life sodium ion batteries J. Mater. Chem. A 5 13204-11 doi: 10.1039/C7TA02370G
    [45]
    Luo C, Shea J J, Huang J 2020 A carboxylate group-based organic anode for sustainable and stable sodium ion batteries J. Power Sources 453 227904 doi: 10.1016/j.jpowsour.2020.227904
    [46]
    Shadike Z, Tan S, Wang Q C, Lin R, Hu E, Qu D, Yang X Q 2021 Review on organosulfur materials for rechargeable lithium batteries Mater. Horiz. 8 471-500 doi: 10.1039/D0MH01364A
    [47]
    Kumar R, Liu J, Hwang J-Y, Sun Y-K 2018 Recent research trends in Li-S batteries J. Mater. Chem. A 6 11582-605 doi: 10.1039/C8TA01483C
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    Figures(9)

    Citation Export
    PDF
    XML

    Article Metrics

    Article Views(400) PDF downloads(49)
    Article Statistics
    Related articles from

    Quick Links

    Contact Us

    • Building A1, Songshan Lake International Innovation Entrepreneurship Community, Dongguan, Guangdong
    • E-mail：editorialoffice@materialsfutures.org
    • Tel：+86-769-89136721

    Relevant Links

    WeChat

    Copyright © 2021 Materials Futures Editorial Office

    Supported by: Beijing Renhe Information Technology Co., Ltd.    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return