Volume 1 Issue 2
June  2022
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Qiang Luo, Zichao Wei, Hanyi Duan, Lei Jin, Rumasha N T Kankanamage, Seth Shuster, Steven L Suib, James F Rusling, Jie He. Templated synthesis of crystalline mesoporous CeO2 with organosilane-containing polymers: balancing porosity, crystallinity and catalytic activity[J]. Materials Futures, 2022, 1(2): 025302. doi: 10.1088/2752-5724/ac7605
Citation: Qiang Luo, Zichao Wei, Hanyi Duan, Lei Jin, Rumasha N T Kankanamage, Seth Shuster, Steven L Suib, James F Rusling, Jie He. Templated synthesis of crystalline mesoporous CeO2 with organosilane-containing polymers: balancing porosity, crystallinity and catalytic activity[J]. Materials Futures, 2022, 1(2): 025302. doi: 10.1088/2752-5724/ac7605
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Templated synthesis of crystalline mesoporous CeO2 with organosilane-containing polymers: balancing porosity, crystallinity and catalytic activity

© 2022 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 1, Number 2
  • Received Date: 2022-04-26
  • Accepted Date: 2022-06-05
  • Revised Date: 2022-06-01
  • Publish Date: 2022-06-22
doi: 10.1088/2752-5724/ac7605
  • 1.

    Department of Chemistry, University of Connecticut, Storrs, CT 06269, United States of America

  • 2.

    Polymer Program, University of Connecticut, Storrs, CT 06269, United States of America

  • 3.

    Institute of Materials Science, University of Connecticut, Storrs, CT 06269, United States of America

  • 4.

    Department of Surgery and Neag Cancer Center, UConn Health, Farmington, CT 06232, United States of America

  • 5.

    School of Chemistry, National University of Ireland Galway, Galway, Ireland

  • Author to whom any correspondence should be addressed.

More Information
    Abstract
  • We report the synthesis of ordered mesoporous ceria (mCeO2) with highly crystallinity and thermal stability using hybrid polymer templates consisting of organosilanes. Those organosilane-containing polymers can convert into silica-like nanostructures that further serve as thermally stable and mechanically strong templates to prevent the collapse of mesoporous frameworks during thermal-induced crystallization. Using a simple evaporation-induced self-assembly process, control of the interaction between templates and metal precursors allows the co-self-assembly of polymer micelles and Ce3+ ions to form uniform porous structures. The porosity is well-retained after calcination up to 900 C. After the thermal engineering at 700 C for 12 h (mCeO2-700-12 h), mCeO2 still has a specific surface area of 96 m2 g-1 with a pore size of 14 nm. mCeO2 is demonstrated to be active for electrochemical oxidation of sulfite. mCeO2-700-12 h with a perfect balance of crystallinity and porosity shows the fastest intrinsic activity that is about 84 times more active than bulk CeO2 and 5 times more active than mCeO2 that has a lower crystallinity.
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