Volume 2 Issue 3
August  2023
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Jiahao Zhang, Chao Ye, Yao Liao, Caihong Sun, Youlian Zeng, Jing Xiao, Zhi Chen, Wei Liu, Xiukang Yang, Ping Gao. Thiophene-functionalized porphyrin complexes as high performance electrodes for sodium ion batteries[J]. Materials Futures, 2023, 2(3): 035101. doi: 10.1088/2752-5724/acdd86
Citation: Jiahao Zhang, Chao Ye, Yao Liao, Caihong Sun, Youlian Zeng, Jing Xiao, Zhi Chen, Wei Liu, Xiukang Yang, Ping Gao. Thiophene-functionalized porphyrin complexes as high performance electrodes for sodium ion batteries[J]. Materials Futures, 2023, 2(3): 035101. doi: 10.1088/2752-5724/acdd86
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Thiophene-functionalized porphyrin complexes as high performance electrodes for sodium ion batteries

© 2023 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 2, Number 3
  • Received Date: 2023-03-26
  • Accepted Date: 2023-06-04
  • Publish Date: 2023-07-13
doi: 10.1088/2752-5724/acdd86

  • 1 Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, People’s Republic of China

  • 2 College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518071, People’s Republic of China

  • 3 Yiyang Hongyuan Rare Earth Co., Ltd, Yiyang 413001, People’s Republic of China

Funds:

This work was financially supported by the National Natural Science Foundation of China (22279109, 22172137), and the Natural Science Foundation of Hunan Province (2021JJ40526, 2022JJ20036).

    Abstract
  • Organic sodium-ion batteries (OSIBs) using eco-friendly organic materials as electrodes have recently received much attention. However, the practical applications of OSIBs are generally limited by the inherent disadvantages of organic electrodes, such as their low conductivity, poor stability, and high solubility in electrolytes. Herein, we presented [5, 10, 15, 20-tetrathienylporphinato] M (II) (MTTP, M=2H, Ni) as new electrode materials in sodium-organic batteries. The incorporation of thiophene functionalized groups and nickel (Ⅱ) ion in the molecular design of porphyrins enabled stable and excellent electrochemical performance in sodium storage systems. Benefiting from multiple charge storage sites and bipolar characteristics, the NiTTP anode has a reversible capacity of 434 mAh g−1 at a current density of 25 mA g−1. An excellent long-term cycling stability and high average voltage were obtained when NiTTP was used as a cathode. In a symmetrical battery, where NiTTP was used as both cathode and anode materials, a high average voltage of 2.3 V and a practical energy density of 93 Wh kg−1 was achieved. These results suggest that the thiophene-based porphyrin derivatives would be promising electrode materials for long-term organic sodium ion batteries for green and stable energy storage.
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