Volume 2 Issue 1
March  2022
Turn off MathJax
Article Contents
Qing Wang, Yinghui Shang, Yong Yang. Quenched-in Liquid in Glass[J]. Materials Futures, 2023, 2(1): 017501. doi: 10.1088/2752-5724/acb8cf
Citation: Qing Wang, Yinghui Shang, Yong Yang. Quenched-in Liquid in Glass[J]. Materials Futures, 2023, 2(1): 017501. doi: 10.1088/2752-5724/acb8cf
shu
Comment •
OPEN ACCESS

Quenched-in Liquid in Glass

© 2023 The Author(s). Published by IOP Publishing Ltd on behalf of the Songshan Lake Materials Laboratory
Materials Futures, Volume 2, Number 1
  • Received Date: 2022-12-21
  • Accepted Date: 2023-02-03
  • Publish Date: 2023-03-17
doi: 10.1088/2752-5724/acb8cf

  • 1 Laboratory for Microstructures, Institute of Materials, Shanghai University, Shanghai 200072, People’s Republic of China

  • 2 Department of Mechanical Engineering, College of Engineering, City University of Hong Kong, Kowloon Tong, Kowloon, Hong Kong, People’s Republic of China

  • 3 Department of Materials Science and Engineering, College of Engineering, City University of Hong Kong, Kowloon Tong, Kowloon, Hong Kong, People’s Republic of China

  • 4 Department of Advanced Design and System Engineering, College of Engineering, City University of Hong Kong, Kowloon Tong, Kowloon, Hong Kong, People’s Republic of China

Funds:

Y Y is thankful for the financial support provided by Research Grants Council, the Hong Kong government through the General Research Fund (Grant Nos. CityU11200719 and CityU11213118) and by the City University of Hong Kong through CityU Strategic Research Grant (Grant No. 7005438). Q W acknowledges the financial support provided by Natural Science Foundation of China (Grant Nos. 52171161, 51871140) and the space utilization system of China Manned Space Engineering (KJZ-YY-NCL08).

    Abstract
  • Glasses have long been considered as frozen liquids because of the similarity between their static amorphous structures. While the modern theories about glass transition suggest that glass transition may result from supercooling of a heterogeneous liquid that contains fast and slow regions, it remains unclear whether such a physical picture applies to metallic glasses, which are a densely packed solid glass that was once believed to be a vitrified homogeneous metallic liquid. However, in the recent work published in Nature Materials, Chang et al provide compelling evidence to show that metallic glasses contain liquid-like atoms that behave as a high-temperature liquid in stress relaxation. Being activated under cyclic loading, this quenched-in liquid results in a fast relaxation process, which is discovered in a variety of metallic glasses. Their results are important and deliver a strong message that metallic glasses have a dynamic microstructure containing liquid- and solid-like atoms. Most importantly, the outcome of their research provides physical insight into the nature of glass-transition in metallic glasses, and also helps unravel their structure-property relations.
    • FullText(HTML)
  • loading
    • References(52)
  • [1]
    Anderson P W 1995 Through the glass lightly Science 267 1615–6
    [2]
    Debenedetti P G and Stillinger F H 2001 Supercooled liquids and the glass transition Nature 410 259–67
    [3]
    Masuhr A, Waniuk T A, Busch R and Johnson W L 1999 Time scales for viscous flow, atomic transport, and crystallization in the liquid and supercooled liquid states of Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 Phys. Rev. Lett. 82 2290–3
    [4]
    Finney J L 1977 Modelling the structures of amorphous metals and alloys Nature 266 309–13
    [5]
    Tanaka H, Kawasaki T, Shintani H and Watanabe K 2010 Critical-like behaviour of glass-forming liquids Nat. Mater. 9 324–31
    [6]
    Nagamanasa K H, Gokhale S, Sood A K and Ganapathy R 2015 Direct measurements of growing amorphous order and non-monotonic dynamic correlations in a colloidal glass-former Nat. Phys. 11 403–8
    [7]
    Hallett J E, Turci F and Royall C P 2018 Local structure in deeply supercooled liquids exhibits growing lengthscales and dynamical correlations Nat. Commun. 9 3272
    [8]
    Sheng H W, Luo W K, Alamgir F M, Bai J M and Ma E 2006 Atomic packing and short-to-medium-range order in metallic glasses Nature 439 419–25
    [9]
    Hirata A, Guan P, Fujita T, Hirotsu Y, Inoue A, Yavari A R, Sakurai T and Chen M 2011 Direct observation of local atomic order in a metallic glass Nat. Mater. 10 28–33
    [10]
    Lubchenko V and Wolynes P G 2007 Theory of structural glasses and supercooled liquids Annu. Rev. Phys. Chem. 58 235–66
    [11]
    Wool R P 2008 Twinkling fractal theory of the glass transition J. Polym. Sci. B 46 2765–78
    [12]
    Tanaka H 1999 Two-order-parameter description of liquids. I. A general model of glass transition covering its strong to fragile limit J. Chem. Phys. 111 3163–74
    [13]
    Tanaka H 1999 Two-order-parameter description of liquids. II. Criteria for vitrification and predictions of our model J. Chem. Phys. 111 3175–82
    [14]
    Wang W H 2012 The elastic properties, elastic models and elastic perspectives of metallic glasses Prog. Mater. Sci. 57 487–656
    [15]
    Berthier L and Biroli G 2011 Theoretical perspective on the glass transition and amorphous materials Rev. Mod. Phys. 83 587–645
    [16]
    Angell C A, Ngai K L, McKenna G B, McMillan P F and Martin S W 2000 Relaxation in glassforming liquids and amorphous solids J. Appl. Phys. 88 3113–57
    [17]
    Karmakar S, Dasgupta C and Sastry S 2015 Length scales in glass-forming liquids and related systems: a review Rep. Prog. Phys. 79 016601
    [18]
    Dyre J C 2006 Colloquium: the glass transition and elastic models of glass-forming liquids Rev. Mod. Phys. 78 953–72
    [19]
    Stevenson J D and Wolynes P G 2010 A universal origin for secondary relaxations in supercooled liquids and structural glasses Nat. Phys. 6 62–68
    [20]
    Stillinger F H and Debenedetti P G 2013 Glass transition thermodynamics and kinetics Annu. Rev. Condens. Matter 4 263–85
    [21]
    Mauro J C, Yue Y, Ellison A J, Gupta P K and Allan D C 2009 Viscosity of glass-forming liquids Proc. Natl Acad. Sci. USA 106 19780–4
    [22]
    Cheng Y Q and Ma E 2011 Atomic-level structure and structure-property relationship in metallic glasses Prog. Mater. Sci. 56 379–473
    [23]
    Miracle D B 2004 A structural model for metallic glasses Nat. Mater. 3 697–702
    [24]
    Ma E 2015 Tuning order in disorder Nat. Mater. 14 547–52
    [25]
    Liu Y H, Wang D, Nakajima K, Zhang W, Hirata A, Nishi T, Inoue A and Chen M W 2011 Characterization of nanoscale mechanical heterogeneity in a metallic glass by dynamic force microscopy Phys. Rev. Lett. 106 1–4
    [26]
    Wang W H 2019 Dynamic relaxations and relaxation-property relationships in metallic glasses Prog. Mater. Sci. 106 100561
    [27]
    Qiao J C et al 2019 Structural heterogeneities and mechanical behavior of amorphous alloys Prog. Mater. Sci. 104 250–329
    [28]
    Zhang P, Maldonis J J, Liu Z, Schroers J and Voyles P M 2018 Spatially heterogeneous dynamics in a metallic glass forming liquid imaged by electron correlation microscopy Nat. Commun. 9 1–7
    [29]
    Yang Q, Peng S X, Wang Z and Yu H B 2020 Shadow glass transition as a thermodynamic signature of β relaxation in hyper-quenched metallic glasses Natl Sci. Rev. 7 1896–905
    [30]
    Küchemann S and Maaß R 2017 Gamma relaxation in bulk metallic glasses Scr. Mater. 137 5–8
    [31]
    Wang B, Wang L J, Shang B S, Gao X Q, Yang Y, Bai H Y, Pan M X, Wang W H and Guan P F 2020 Revealing the ultra-low-temperature relaxation peak in a model metallic glass Acta Mater. 195 611–20
    [32]
    Yu H B and Samwer K 2014 Atomic mechanism of internal friction in a model metallic glass Phys. Rev. B 90 144201
    [33]
    Chang C, Zhang H P, Zhao R, Li F C, Luo P, Li M Z and Bai H Y 2022 Liquid-like atoms in dense-packed solid glasses Nat. Mater. 21 1240–5
    [34]
    Vila-Costa A, Gonzalez-Silveira M, Rodríguez-Tinoco C, Rodríguez-López M and Rodriguez-Viejo J 2022 Emergence of equilibrated liquid regions within the glass Nat. Phys. Phys. 19 114–9
    [35]
    Song S, Zhu F and Chen M 2022 Universal scaling law of glass rheology Nat. Mater. 21 404–9
    [36]
    Yu H B, Wang W H, Bai H Y, Wu Y and Chen M W 2010 Relating activation of shear transformation zones to β relaxations in metallic glasses Phys. Rev. B 81 1–4
    [37]
    Yu H B, Richert R and Samwer K 2017 Structural rearrangements governing Johari-Goldstein relaxations in metallic glasses Sci. Adv. 3 e1701577
    [38]
    Wang Q et al 2015 Unusual fast secondary relaxation in metallic glass Nat. Commun. 6 7876
    [39]
    Wang Q, Liu J J, Ye Y F, Liu T T, Wang S, Liu C T, Lu J and Yang Y 2017 Universal secondary relaxation and unusual brittle-to-ductile transition in metallic glasses Mater. Today 20 293–300
    [40]
    Wu Y et al 2021 Substantially enhanced plasticity of bulk metallic glasses by densifying local atomic packing Nat. Commun. 12 1–9
    [41]
    Cangialosi D, Boucher V M, Alegría A and Colmenero J 2013 Direct evidence of two equilibration mechanisms in glassy polymers Phys. Rev. Lett. 111 1–5
    [42]
    Gallino I, Cangialosi D, Evenson Z, Schmitt L, Hechler S, Stolpe M and Ruta B 2018 Hierarchical aging pathways and reversible fragile-to-strong transition upon annealing of a metallic glass former Acta Mater. 144 400–10
    [43]
    Perez-De Eulate N G and Cangialosi D 2018 The very long-term physical aging of glassy polymers Phys. Chem. Chem. Phys. 20 12356–61
    [44]
    Huo L S, Zeng J F, Wang W H, Liu C T and Yang Y 2013 The dependence of shear modulus on dynamic relaxation and evolution of local structural heterogeneity in a metallic glass Acta Mater. 61 4329–38
    [45]
    Wang Q et al 2014 Superior tensile ductility in bulk metallic glass with gradient amorphous structure Sci. Rep. 4 4757
    [46]
    Ye J C, Lu J, Liu C T, Wang Q and Yang Y 2010 Atomistic free-volume zones and inelastic deformation of metallic glasses Nat. Mater. 9 619–23
    [47]
    Sun B A, Hu Y C, Wang D P, Zhu Z G, Wen P, Wang W H, Liu C T and Yang Y 2016 Correlation between local elastic heterogeneities and overall elastic properties in metallic glasses Acta Mater. 121 266–76
    [48]
    Lewandowski J J, Wang W H and Greer A L 2005 Intrinsic plasticity or brittleness of metallic glasses Phil. Mag. Lett. 85 77–87
    [49]
    Ding J, Patinet S, Falk M L, Cheng Y and Ma E 2014 Soft spots and their structural signature in a metallic glass Proc. Natl Acad. Sci. USA 111 14052–6
    [50]
    Guan P, Chen M and Egami T 2010 Stress-temperature scaling for steady-state flow in metallic glasses Phys. Rev. Lett. 104 1–4
    [51]
    Ma J et al 2019 Fast surface dynamics enabled cold joining of metallic glasses Sci. Adv. 5 eaax7256
    [52]
    Li X et al 2020 Ultrasonic plasticity of metallic glass near room temperature Appl. Mater. Today 21 100866
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    Figures(1)

    Citation Export
    PDF
    XML

    Article Metrics

    Article Views(40) PDF downloads(30)
    Article Statistics
    Related articles from

    Quick Links

    Contact Us

    • Building A1, Songshan Lake International Innovation Entrepreneurship Community, Dongguan, Guangdong
    • E-mail：editorialoffice@materialsfutures.org
    • Tel：+86-769-89136672

    Relevant Links

    WeChat

    Copyright © 2021 Materials Futures Editorial Office

    Supported by: Beijing Renhe Information Technology Co., Ltd.    

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return